کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5399490 | 1505903 | 2015 | 5 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Detailed mechanism of the ligand-to-metal energy transfer of silica-coated Tb(III) complex with p-sulfonatothiacalix[4]arene
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موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی تئوریک و عملی
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چکیده انگلیسی
The energy transfer mechanism, which provides the feeding of the excited 5D4 level of Tb(III), has been studied by photoluminescence spectroscopy in the Tb(III) complex with p-sulfonato-thiacalix[4]arene doped into the silica nanoparticles. The quantitative evaluation of the rate constants of each energy transfer step highlights two channels of the energy transfer from the singlet ligand-centered level to the 5D4 level. The channel one occurs via the triplet ligand level S1âT1â5D4, the second channel comes about via the higher levels of Tb(III) S1â5D3â5D4. The latter channel determines the rate of the luminescence decay of the 5D4 level. The high luminescence efficiency and enhanced thermo- and photo-stabilities make the Tb(III) complexes doped into the silica nanoparticles a promising nanomaterial for medical and bioanalytical applications.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Luminescence - Volume 157, January 2015, Pages 158-162
Journal: Journal of Luminescence - Volume 157, January 2015, Pages 158-162
نویسندگان
Georgy M. Safiullin, Victor G. Nikiforov, Nikolay A. Davydov, Asiya R. Mustafina, Svetlana Ye. Soloveva, Vladimir S. Lobkov, Kev M. Salikhov, Alexander I. Konovalov,