کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5399633 | 1505901 | 2015 | 29 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Reversible photoluminescence in spiropyran-modified porous silicon
ترجمه فارسی عنوان
فوتولومینسانس برگشت پذیر در سیلیکون متخلخل متحرک اصلاح شده اسپیروپیان
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کلمات کلیدی
اسپیروپیران، سیلیکون متخلخل، فوتولومینسانس برگشت پذیر،
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی تئوریک و عملی
چکیده انگلیسی
Spiropyran-modified porous silicon (spiro-PS) was used for the first time as an organic-inorganic hybrid material by using reversible photoluminescence (PL). Before spiropyran modification, the peak wavelength from PS was approximately 600Â nm. Subsequent spiropyran modification strongly quenched the PL intensity, from 15,000 to 2000 counts. However, under UV light irradiation, the PL intensity from spiro-PS was increased gradually to 20,000 counts because of the photoinduced ring opening from a colorless spiropyran (SP-form) to a colored merocyanine (MC-form). Furthermore, the resulting peak wavelength of the PL of an MC-PS sample red-shifted from 600 to 650Â nm, and the PL intensity was higher than that of unmodified PS. Because the fluorescence emission band (500-700Â nm) of PS substantially overlapped the absorption band (500-700Â nm) of the MC-form of spiropyran, the energy transfer from the PS (donor) to the open-ring-state MC-form (acceptor) occurs efficiently. The intensity of the PL from spiro-PS can be reversibly modulated using a heat stimulus. The current demonstrations have potential in reversible solid-state lighting or data storage applications.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Luminescence - Volume 159, March 2015, Pages 246-250
Journal: Journal of Luminescence - Volume 159, March 2015, Pages 246-250
نویسندگان
Chen-Yu Lee, Chih-Hsuan Hu, Sheng-Lin Cheng, Chih-Chien Chu, Vincent K.S. Hsiao,