کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5399889 | 1505909 | 2014 | 5 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Optical spectroscopy of the Nd3+ and Nd3+-Gd3+/Yb3+ centres in BaF2 single crystals and calculations on lanthanide-doped BaF2
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی تئوریک و عملی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
Absorption and site-selective laser spectroscopy of BaF2 single crystals homogeneously doped with Nd3+ ions as well as heterogeneously doped with Nd3+ and either Gd3+ or Yb3+ ions, performed at 10Â K, is presented. In each case a single centre, assigned to be of C3v symmetry, is dominant. A heterogeneous Nd3+-RE3+ (RE being either Nd or Yb) is also present in each of the double doped crystals. Energy levels for six multiplets of the single Nd3+ centre and for three multiplets for each Nd3+-RE3+ centre are presented together with the 4F3/2 (R) multiplet fluorescence lifetime for each centre. Calculations give comparable solution energies for C3v and C4v symmetry Nd3+ centres in BaF2; the C3v symmetry configuration has lower energy for the preceding lanthanides while C4v is favoured from Sm3+ onwards.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Luminescence - Volume 151, July 2014, Pages 106-110
Journal: Journal of Luminescence - Volume 151, July 2014, Pages 106-110
نویسندگان
Marjorie Mujaji, James Burrows, Robert A Jackson,