کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5399936 | 1505902 | 2015 | 7 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
The fluorescence decay times and quantum efficiencies of 1,4,5,8-naphthalisoimides
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی تئوریک و عملی
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: The fluorescence decay times and quantum efficiencies of 1,4,5,8-naphthalisoimides The fluorescence decay times and quantum efficiencies of 1,4,5,8-naphthalisoimides](/preview/png/5399936.png)
چکیده انگلیسی
Presented herein are the luminescence properties of several 1,4,5,8- polinahthalisoimides. The luminescence decay curves after deconvolution exhibit three decay times: Ï1, Ï2, and Ï3.The luminescence lifetimes change along with the growth of excitation energy, as well as the contribution of each luminescence decay mechanism (A1, A2, and A3). The manner of change is distinct for one sample, namely, the pure E-isomer, in comparison to the others. The radiative deexcitation coupled with radiationless vibrational energy transfer to other luminescence centers, mainly other isomer units, is discussed as a possible deexcitation mechanism of fluorescence. The Kasha-Vavilov empirical rule is not fulfilled for the studied samples, as the luminescence quantum efficiency (ΦF) distinctly depends on the excitation wavelength (λexc). The quantum yield of one sample (about 63% of Z-isomer) is quite high, at 1%.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Luminescence - Volume 158, February 2015, Pages 103-109
Journal: Journal of Luminescence - Volume 158, February 2015, Pages 103-109
نویسندگان
Zbigniew Mazurak, Andrzej Wanic, Jerzy Karolczak, Maria Czaja,