کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5400000 | 1505902 | 2015 | 9 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Effect of triplet-triplet absorption on time-resolved phosphorescence
ترجمه فارسی عنوان
اثر جذب سه گانه سه بعدی بر فسفر سنجی زمانی حل شده
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی تئوریک و عملی
چکیده انگلیسی
Molecular radiative transport, consisting in consecutive emission-absorption events by atoms or molecules of the same species, is studied in the case of excited-state absorption, a situation relevant to the phosphorescence of polycyclic aromatic hydrocarbons. This type of transfer differs in a number of ways from the better studied atomic resonance and molecular fluorescence cases, and leads to decays with a very distinctive form. A simple 1D model is introduced and used to discuss qualitatively the phosphorescence build-up and the phosphorescence decay in the presence of reabsorption. A new empirical phosphorescence decay law is also presented and justified on the basis of a phenomenological equation. The phosphorescence build-up and the phosphorescence decay in the presence of reabsorption are discussed and confronted with experimental results obtained for both normal and perdeuterated coronene.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Luminescence - Volume 158, February 2015, Pages 510-518
Journal: Journal of Luminescence - Volume 158, February 2015, Pages 510-518
نویسندگان
Tiago Palmeira, Mário N. Berberan-Santos,