کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5400928 | 1392704 | 2012 | 4 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Observation of charge transfer process for optical emission of rare-earth dopant using electric probing technique
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی تئوریک و عملی
پیش نمایش صفحه اول مقاله
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چکیده انگلیسی
Charge propagation dynamics for the excitation and de-excitation of samarium doped titanium dioxide (TiO2:Sm) were observed by an electric measurement technique, namely, the phase response of complex impedance to step-function UV irradiation. The probing frequency for the impedance measurement was widely changed, and a critical frequency that emphasizes a specific charge propagation path was found. Above the critical frequency of 1Â kHz the transitions from the photo-excited state to ground state progressed via a rapid, and a slow charge propagation path. Through a comparison of the frequency responses obtained under continuous UV light (photo-excited state) and in the dark (ground state), the rapid path was assigned to charge recombination in a defect-dopant complex in TiO2:Sm, which is consistent with the persistence of luminescence observed in conventional optical measurements. The slow path that is not associated with the optical transition was explained by a dissipation of excited charges. Similar path consistent with the charge dissipation explanation was confirmed below the critical frequency <1Â kHz.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Luminescence - Volume 132, Issue 12, December 2012, Pages 3129-3132
Journal: Journal of Luminescence - Volume 132, Issue 12, December 2012, Pages 3129-3132
نویسندگان
M. Ishii, S. Harako, X. Zhao, S. Komuro, B. Hamilton,