Synthesis, spectral and photophysical properties of novel phthalocyanines bearing bulky phenantroxy moiety

► New metallophthalocyanines (1a-1d) were synthesized. ► These new phthalocyanine derivatives show the enhanced solubility in organic solvents. ► The spectral and photophysical properties of TiO(IV), zinc (II) and Mg(II) phthalocyanine (1a-1c) are investigated in DMSO and toluene. ► Ground state electronic absorption and fluorescence spectra.