کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5402229 | 1392729 | 2011 | 5 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Synthesis, characterization and spectroscopic investigation of new tetrakis(acetylacetonato)thulate(III) complexes containing alkaline metals as countercations
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی تئوریک و عملی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
In this work a series of tetrakis complexes C[Tm(acac)4], where C+=Li+, Na+ and K+ countercations and acac=acetylacetonate ligand, were synthesized and characterized for photoluminescence investigation. The relevant aspect is that these complexes are water-free in the first coordination sphere. The emission spectra of the tetrakis Tm3+-complexes present narrow bands characteristic of the 1G4â3H6 (479Â nm), 1G4â3F4 (650Â nm) and 1G4â3H5 (779Â nm) transitions of the Tm3+ ion, with the blue emission color at 479Â nm as the most prominent one. The lifetime values (Ï) of the emitting 1G4 level of the C[Tm(acac)4] complexes were 344, 360 and 400Â ns for the Li+, Na+ and K+ countercations, respectively, showing an increasing linear behavior versus the ionic radius of the alkaline ion. An efficient intramolecular energy transfer process from the triplet state (T) of the ligands to the emitting 1G4 state of the Tm3+ ion is observed. This fact, together with the absence of water molecules in first coordination sphere, allows these tetrakis Tm3+-complexes to act as efficient blue light conversion molecular devices.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Luminescence - Volume 131, Issue 1, January 2011, Pages 99-103
Journal: Journal of Luminescence - Volume 131, Issue 1, January 2011, Pages 99-103
نویسندگان
M.A. Guedes, T.B. Paolini, M.C.F.C. Felinto, J. Kai, L.A.O. Nunes, O.L. Malta, H.F. Brito,