کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5402660 | 1392739 | 2009 | 4 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Electronic structure of the Sr2MgSi2O7:Eu2+ persistent luminescence material
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی تئوریک و عملی
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Electronic structure of the Sr2MgSi2O7:Eu2+ persistent luminescence material Electronic structure of the Sr2MgSi2O7:Eu2+ persistent luminescence material](/preview/png/5402660.png)
چکیده انگلیسی
The electronic structures of the distrontium magnesium disilicate (Sr2MgSi2O7(:Eu2+)) materials were studied by a combined experimental and theoretical approach. The UV-VUV synchrotron radiation was applied in the experimental study while the electronic structures were investigated theoretically by using the density functional theory. The structure of the valence and conduction bands and the band gap energy of the material as well as the position of the Eu2+ 4f ground state were calculated. The calculated band gap energy (6.7Â eV) agrees well with the experimental value of 7.1Â eV. The valence band consists mainly of the oxygen states and the bottom of the conduction band of the Sr states. The calculated occupied 4f ground state of Eu2+ lies in the energy gap of the host though the position depends strongly on the Coulomb repulsion strength. The position of the 4f ground state with respect to the valence and conduction bands is discussed using the theoretical and experimental evidence available.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Luminescence - Volume 129, Issue 12, December 2009, Pages 1560-1563
Journal: Journal of Luminescence - Volume 129, Issue 12, December 2009, Pages 1560-1563
نویسندگان
Jorma Hölsä, Marco Kirm, Taneli Laamanen, Mika Lastusaari, Janne Niittykoski, Pavel Novák,