کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5402787 | 1392741 | 2010 | 7 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Modulated photophysics of 2-anthracene sulphonate in micellar assembly
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی تئوریک و عملی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
The association of a non-ionic surfactant of polyoxyethylene-p-(1,1,3,3-tetramethylbutyl)phenyl ether (Triton X) series with 2-AS in aqueous solution has been studied by means of steady-state, time-resolved fluorescence and fluorescence anisotropy techniques. The effect of the hydrophobic chain length on the structural dynamism of the fluorophore has been reported. Experimental results demonstrate that the equilibrium of this dynamism is sensitive to the environment. The association constant of the probe molecule with the non-ionic micelles of Triton X (TX), location of the probe in the micellar environment, have been determined from the change in emission characteristics of the probe as a function of surfactant concentration. The rate constant of quenching and mode of quenching of probe in micellar media have been ascertained. Quantitative estimates of the micropolarity at the binding sites of the probe molecule have been determined. Some of the environment-dependent relevant fluorescence parameters, fluorescence anisotropy (r), have been monitored for exploring the imposed motional restriction of the microenvironment around the probe. An attempt has been made to correlate the steady-state results with time resolved study.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Luminescence - Volume 130, Issue 6, June 2010, Pages 1106-1112
Journal: Journal of Luminescence - Volume 130, Issue 6, June 2010, Pages 1106-1112
نویسندگان
Dipak Kumar Rana, Arindam Sarkar, Sayaree Dhar, Tapas Kumar Mandal, Subhash Chandra Bhattacharya,