کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5403420 | 1392758 | 2007 | 10 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Structural and luminescence studies of trivalent europium complexes with pentaethylene glycol and 18-crown-6 ligands in the presence of picrate anion
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی تئوریک و عملی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
Two new isostructural complexes of europium picrate (Eu-Pic) with pentaethylene glycol (EO5) and 18-crown-6 (18C6) ligands formed complexes of molecular formula [Eu(Pic)2(18C6)]+(Pic)âI and [Eu(Pic)2(EO5)]+(Pic)âII have been isolated and characterised. Compound I showed 10-coordination number through six oxygen atoms from the 18C6 ligand and two bidentate picrate anions. Meanwhile, compound II exhibited 9-coordination number via six oxygen atoms from EO5 ligand, two oxygen atoms from a bidentate and one oxygen atom from monodentate picrate anions. Photoluminescence (PL) spectra of the solid-state europium complexes display sharp lines which are assigned to 5D0â7F0-4 and 5D1â7F1,2,4 transitions. No emission of polyether ligands is observed, indicating that the energy transfer from the polyether ligands to the Eu3+ ion is quite efficient. The PL spectra of [Eu(Pic)2(OH2)6]+(Pic)â·6H2O III, [Eu(NO3)3(OH2)3]·(18C6) IV, [Eu(NO3)3·6H2O] V and Eu2O3VI are also observed. Compounds I-IV exhibited high Ω2 intensity parameter values, namely 16.93, 10.23, 17.10 and 12.35 (in units of 10â20 cm2), respectively. These relatively high values reflect the hypersensitive behaviour of the 5D0â7F2 transition and indicate that the Eu3+ ion is located in a highly polarisable chemical environment.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Luminescence - Volume 126, Issue 2, October 2007, Pages 871-880
Journal: Journal of Luminescence - Volume 126, Issue 2, October 2007, Pages 871-880
نویسندگان
Muhammad I. Saleh, Eny Kusrini, Bahruddin Saad, Rohana Adnan, Abdussalam S. Mohamed, Bohari M. Yamin,