کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5403747 | 1392766 | 2008 | 6 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Synthesis of 2,3-dimorpholino-6-aminoquinoxaline derivatives and application to a new intramolecular fluorescent probe
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موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی تئوریک و عملی
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چکیده انگلیسی
Two fluorescent monomers having a quinoxaline skeleton, N-(2,3-dimorpholinoquinoxalin-6-yl)acrylamide (QxA) and N-(1-(2,3-dimorpholinoquinoxalin-6-ylamino)prop-2-yl)methacrylamide (QxAlaMA), were synthesized. Thermo-responsive copolymers of N-isopropylacrylamide (NIPAM) and a small amount of a fluorescent monomer were synthesized and their fluorescence properties investigated. The fluorescent monomers showed intense solvatochromism in their fluorescence. The wavelength at the maximum fluorescence intensity of the QxAlaMA-labeled PNIPAM dramatically blue-shifted and the fluorescence intensity of the QxA-labeled PNIPAM significantly increased around the transition temperature. It was found that these fluorescent dyes can sense and report the thermo-responsive behavior of the PNIPAM in water. Both QxAlaMA and QxA were demonstrated to be applicable to new intramolecular fluorescent probes.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Luminescence - Volume 128, Issue 4, April 2008, Pages 625-630
Journal: Journal of Luminescence - Volume 128, Issue 4, April 2008, Pages 625-630
نویسندگان
Yuriko Matsumura, Akira Katoh,