کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5403808 | 1392768 | 2008 | 9 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Size-dependent microstructure and europium site preference influence fluorescent properties of Eu3+-doped Ca10(PO4)6(OH)2 nanocrystal
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی تئوریک و عملی
پیش نمایش صفحه اول مقاله

چکیده انگلیسی
In this study, Eu3+-doped nanocrystalline Ca10(PO4)6(OH)2 (Ca10âxEux(PO4)6(OH)2) with different particle sizes have been prepared by the thermal decomposition of precursors. Size-dependent microstructure could be observed in nanocrystalline Ca10âxEux(PO4)6(OH)2. The lattices of Ca10âxEux(PO4)6(OH)2 nanocrystals were more distorted in comparison with the bulk, and the smaller the particle size, the more distorted the lattices. Room temperature photoluminescence showed europium site preference was also size-dependent, with the majority of Eu3+ ions occupying Ca(II) sites in the bulk, but more and more Eu3+ ions occupying Ca(I) sites in Ca10âxEux(PO4)6(OH)2 with decreasing particle size. Fluorescent properties of Ca10âxEux(PO4)6(OH)2 were considered to be influenced by both microstructure and site preference of Eu3+ ions. An abnormal strong intensity of 5D0-7F0 transition was observed in bulk and larger Ca10âxEux(PO4)6(OH)2 nanocrystals, but the relative intensities of 5D0-7F0 transition to 5D0-7F1,2,3,4 transition of Eu3+ became weaker as the particle sizes decreased. As the particle sizes became smaller, the ratios of the red emission transition (5D0-7F2) to the orange emission transition (5D0-7F1) (R/O values) first increased by comparing the bulk sample with 96Â nm sample, and then decreased by comparing 96Â nm sample to 57Â nm sample. The quenching concentrations of Ca10âxEux(PO4)6(OH)2 samples increased with decreasing particle size. Possible mechanisms responsible for these phenomena were proposed. Since nanosized Ca10âxEux(PO4)6(OH)2 showed higher fluorescent intensities, higher R/O values and higher quenching concentrations, this material is considered to be a promising phosphor.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Luminescence - Volume 128, Issue 3, March 2008, Pages 428-436
Journal: Journal of Luminescence - Volume 128, Issue 3, March 2008, Pages 428-436
نویسندگان
Mei Long, Fashui Hong, Wei Li, Fuchun Li, Haiyan Zhao, Yuanqi Lv, Huixin Li, Feng Hu, Lingdong Sun, Chunhua Yan, Zhenggui Wei,