کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5404061 | 1392771 | 2006 | 9 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Effect of solvent on the quenching of fluorescence of safranine T(3,7-diamino-2,8-dimethyl-5-phenylphenazinium chloride) in binary solvent mixtures
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی تئوریک و عملی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
Fluorescence quenching of 3,7-diamino-2, 8-dimethyl-5-phenylphenazinium chloride (safranine T (ST)) by halides and pseudo halides in binary solvent mixtures was investigated by steady-state fluorescence spectroscopy. Several parameters, such as dielectric constant, viscosity coefficient, ET30 and fluorescence quantum yield have been investigated as a function of solvent compositions. In mixed solvents ST has been used as a probe for studying the microheterogenity of the mixture. The preferential solvations around ST in the excited state were determined. The Stern-Volmer quenching constants at different compositions of solvent mixtures were determined and the rational analysis of the results was attempted.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Luminescence - Volume 121, Issue 2, December 2006, Pages 488-496
Journal: Journal of Luminescence - Volume 121, Issue 2, December 2006, Pages 488-496
نویسندگان
Pijus Kanti Khatua, Sujan Chatterjee, S.C. Bhattacharya,