کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
5404102 1505930 2007 7 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
A time-dependent modified Redfield theory for absorption spectra applied to light-harvesting systems
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی تئوریک و عملی
پیش نمایش صفحه اول مقاله
A time-dependent modified Redfield theory for absorption spectra applied to light-harvesting systems
چکیده انگلیسی
A time-dependent modified Redfield theory is used to calculate the linear absorption spectrum for an ensemble of B850 rings of the light-harvesting system LH2 of purple bacteria. This theory is an extension of the standard modified Redfield theory without invoking the Markov approximation. The results for the modified Redfield theory with and without Markov approximation are compared to the spectra obtained from a time-local second-order perturbation theory in the system-bath coupling sometimes also called time-dependent Redfield theory. The influence of the shape of the spectral density on the linear absorption spectrum is demonstrated for single samples and in the ensemble average. Non-Markovian effects clearly show up in the high-energy part of the static absorption line shapes. Among the different spectral densities studied is one of a purple bacterium obtained earlier by a molecular dynamics simulation.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Luminescence - Volume 125, Issues 1–2, July–August 2007, Pages 126-132
نویسندگان
, , ,