کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5404403 | 1505933 | 2006 | 7 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Effect of temperature on emission of MEH-PPV/PS solid-state solution
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی تئوریک و عملی
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Effect of temperature on emission of MEH-PPV/PS solid-state solution Effect of temperature on emission of MEH-PPV/PS solid-state solution](/preview/png/5404403.png)
چکیده انگلیسی
The polymer-polymer interaction of poly[2-methoxy-5-(2â²-ethylhexyloxy)-1,4-p-phenylenevinylene] (MEH-PPV) in blends with polystyrene (PS) was studied. Photoluminescence spectra of blend films present a new well-resolved peak at 10Â K, which appears at lower wavelengths, being associated to an intrachain transition. The emission line shape of MEH-PPV/PS blends was analyzed using a molecular exciton theory, supposing two radiative processes, allied to non-localized (aggregate states) and localized (intrachain) transitions. The temperature dependence of the intrachain transition shows an energy transfer process from localized to non-localized state above 180Â K. The electronic structure based on the experimental results is discussed and the electronic-vibrational coupling parameter (Huang-Rhys factor) of MEH-PPV/PS blend was obtained.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Luminescence - Volume 116, Issues 1â2, JanuaryâFebruary 2006, Pages 87-93
Journal: Journal of Luminescence - Volume 116, Issues 1â2, JanuaryâFebruary 2006, Pages 87-93
نویسندگان
Alexandre Marletta, Vanessa C. Gonçalves, Débora T. Balogh,