کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5407983 | 1506528 | 2017 | 9 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Conductometry and Density Functional Theory studies on the interactions of sodium polystyrenesulfonate with 1-butyl-3-methylimidazolium bromide in aqueous solution
دانلود مقاله + سفارش ترجمه
دانلود مقاله ISI انگلیسی
رایگان برای ایرانیان
کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی تئوریک و عملی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
Electrical conductance of sodium polystyrene sulfonate (NaPSS) have been measured in aqueous solutions of 1-butyl-3-methylimidazolium bromide ([BMIm]Br) at three different temperatures TÂ =Â (288.15, 298.15 and 308.15) K. The scaling theory is applied for the explanation of electrical conductance of polyelectrolytes. From the obtained results can be seen that the fraction of uncondensed counterions is decreased by increasing temperature and concentration of [BMIm]Br. Also, conductivity measurements of 1-butyl-3-methylimidazolium bromide were carried out in aqueous solution of sodium polystyrene sulfonate. Data analysis was performed by the Quint-Viallard (QV) conductivity equation and low concentration chemical model (lcCM). Limiting molar conductivities of [BMIm]Br (Î0) and the association constant (KA) were determined. Molar conductivity of [BMIm]Br in aqueous solutions of NaPSS was increased with increasing temperature. The values of activation energy for viscous flow and the values of activation enthalpy of charge transport were calculated. The results of Quantum chemical calculations were confirmed the existence of hydrogen bonding between [BMIm]+ and [PSS]â.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Molecular Liquids - Volume 243, October 2017, Pages 324-332
Journal: Journal of Molecular Liquids - Volume 243, October 2017, Pages 324-332
نویسندگان
Abbas Mehrdad, Elahe Parvini,