کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5408184 | 1506524 | 2017 | 16 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Molecular interaction studies of l-alanine and l-phenylalanine in water and in aqueous citric acid at different temperatures using volumetric, viscosity and ultrasonic methods
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی تئوریک و عملی
پیش نمایش صفحه اول مقاله

چکیده انگلیسی
Densities, ultrasonic speeds and viscosities of l-alanine and l-phenylalanine in water and in 0.1 mol·kgâ 1 aqueous citric acid solutions were measured over the temperature range (298.15 to 313.15) K with interval of 5 K at atmospheric pressure. From these experimental data apparent molar volume, limiting apparent molar volume and the slope, partial molar expansibilities, adiabatic compressibility, transfer volume, Falkenhagen coefficient, Jone-Dole's coefficient, the temperature derivative of Jone-Dole's coefficient, intermolecular free length, specific acoustic impedance, and molar compressibility were calculated. The results are interpreted in terms of solute - solute and solute-solvent interactions in these systems. It has also been observed that l-alanine acts as a structure breaker whereas l-phenylalanine acts as a structure maker in aqueous citric acid.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Molecular Liquids - Volume 247, December 2017, Pages 75-83
Journal: Journal of Molecular Liquids - Volume 247, December 2017, Pages 75-83
نویسندگان
Dinesh Kumar, Shashi Kant Lomesh, Vikas Nathan,