کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
5408301 1506530 2017 29 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Cloud point-magnetic dispersive solid phase extraction for the spectrofluorometric determination of citalopram
ترجمه فارسی عنوان
ابر استخراج نقطه فیزیکی مغناطیسی پراکنده برای تعیین اسپکتروفتومتریک سیتالوپرام
کلمات کلیدی
تعیین سیتالوپرام، استخراج نقطه ابر، نانوکامپوزیت فریت روی نیکل، اسپکتروفتومتری،
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی تئوریک و عملی
چکیده انگلیسی
Cloud point-magnetic solid phase extraction was used for the purpose of extraction and preconcentration of citalopram prior to its determination by the spectrofluorometric method. Non-ionic surfactant Triton X-100 was used for cloud point extraction and nickel zinc ferrite magnetic nanocomposite was used as a sorbent for the adsorption of surfactant rich phase. The implemented method involves initial extraction of the target analytes by CPE in the micelles of a non-ionic surfactant medium followed by using nickel zinc ferrite magnetic nanocomposite to retrieve the micellar phase. Magnetic materials are then collected by applying an adscititious magnetic field to overcome the need for specific steps associated with CPE such as refrigeration of the condensed micellar phase to reduce its viscosity, centrifugation to separate the surfactant-rich phase and/or appropriate apparatus that enable direct sampling of the surfactant-rich phase. Under the optimal extraction conditions (i.e. pH: 9, adsorbent dosage: 60 mg, Triton X-100 concentration: 50 mg and t = 50 °C) the linear dynamic range and RSD were 3.00-800 ng mL− 1 and 2.93%, respectively. A limit of detection of 0.42 ng mL− 1 of citalopram was obtained for the method. Obtained results showed successful application of the method for the analysis of citalopram in the real samples.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Molecular Liquids - Volume 241, September 2017, Pages 43-48
نویسندگان
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