کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5408311 | 1506530 | 2017 | 23 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Supra molecular mechanism of the removal of 17-β-estradiol endocrine disturbing pollutant from water on functionalized iron nano particles
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موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی تئوریک و عملی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
β-Estradiol residue in water is very dangerous and unacceptable due to its endocrine disturbing and carcinogenetic nature. Therefore, fast, effective and eco-friendly removal method of β-estradiol is described from water. The maximum removal of β-estradiol from water was 82% with 600 μg Lâ 1 amount of 17-β-estradiol, 60 min agitation time, 6.0 g Lâ 1 amount of functionalized iron nano particles, 11.5 pH and 25 °C temperature. Thermodynamic parameters confirmed the spontaneous and exothermic uptake of 17-β-estradiol. The uptake of 17-β-estradiol followed first order reaction and the mechanism of uptake was through liquid film diffusion. The supra-molecular mechanism of β-estradiol interaction with functionalized iron nano particles is described. The reported method is fast, effective and eco-friendly and can be applied for the uptake of β-estradiol from water at laboratory, pilot and industrial levels in any water system.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Molecular Liquids - Volume 241, September 2017, Pages 123-129
Journal: Journal of Molecular Liquids - Volume 241, September 2017, Pages 123-129
نویسندگان
Imran Ali, Zeid A. Alothman, Abdulrahman Alwarthan,