کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5408644 | 1506538 | 2017 | 23 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Stability constants of the ternary nickel(II) complexes with salicylic acid and selected amino acids
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی تئوریک و عملی
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Stability constants of the ternary nickel(II) complexes with salicylic acid and selected amino acids Stability constants of the ternary nickel(II) complexes with salicylic acid and selected amino acids](/preview/png/5408644.png)
چکیده انگلیسی
In this work, we present the study of the ternary Nickel(II) complexes with salicylic acid and the amino acids: aspartic acid (H2Asp, H2L), glutamic acid (H2Glu, H2L), cysteine (H2Cys, H2L) and histidine (HHis, HL) formed in aqueous solution at 25 °C and 1.0 mol·dmâ 3 NaCl as the ionic medium. The analysis of the potentiometric data by means of the computational least-squares program LETAGROP, indicate the formation of the ternary complexes [Ni(Sal)H2L]2 â n, [Ni(Sal)HL]1 â n, [Ni(Sal)L]â n, [Ni(Sal)L(OH)]â(1 + n). Where n = 1 for histidine and 2 for the other amino acids. The relative stability of the ternary complexes compared to the binary ones were evaluated considering the values of â log K, log X and % R.S. Species distribution diagrams as a function of pH were briefly discussed.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Molecular Liquids - Volume 233, May 2017, Pages 288-291
Journal: Journal of Molecular Liquids - Volume 233, May 2017, Pages 288-291
نویسندگان
Alejandro Pérez, Waleska Madden, Lino Hernández, Edgar Del Carpio, Vito Lubes,