Modification of Bruggeman's formula for binary liquid mixtures with hydrogen bonds

The measured permittivity of binary liquid mixture with hydrogen bonds is larger than that of any component at some proportions or at some frequencies, which is not accurately consistent with Bruggeman's formula. Mathematical analysis about this phenomenon was made and compared with experimental data, the results indicates that there is a limitation of Bruggeman's formula about liquid mixture. Furthermore, a correction term was introduced by Debye relation model about binary liquid mixture with 1 hydrogen acceptor and donator. The numerical results obtained from modified Bruggeman's formula agrees approximately with experimental results.