کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5408958 | 1506533 | 2017 | 7 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Experimental measurements and equilibrium study of functional d-sorbitol in good and anti-solvent binary mixtures
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی تئوریک و عملی
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Experimental measurements and equilibrium study of functional d-sorbitol in good and anti-solvent binary mixtures Experimental measurements and equilibrium study of functional d-sorbitol in good and anti-solvent binary mixtures](/preview/png/5408958.png)
چکیده انگلیسی
The solid-liquid equilibrium (SLE) of d-sorbitol in (ethanol + acetonitrile) binary solvent mixtures was explored at temperatures ranging from 278.15 K to 333.15 K under 0.1 MPa. For the temperature range investigated, the equilibrium solubility varies with the composition of the solvent and temperature. The equilibrium solubility data were then modelled using modified Apelblat equation, a variant of the combined nearly ideal binary solvent/Redich-Kister (GSM) model and Jouyban-Acree model. Computational results showed that the modified Apelblat equation and CNIBS/R-K model have the low mean deviation (MD). In addition, the thermodynamic properties of the solution process, including the Gibbs energy, enthalpy, and entropy were calculated by the van't Hoff analysis.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Molecular Liquids - Volume 238, July 2017, Pages 296-302
Journal: Journal of Molecular Liquids - Volume 238, July 2017, Pages 296-302
نویسندگان
Yonghong Hu, Yemin Yu, Yuhao Zhang, Wenge Yang, Tao Li, Renlun Deng, Min Jiang,