کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
5410254 1506556 2016 7 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Study of molecular interaction in the mixtures of benzene + methyl acrylate/butyl acrylate through dielectric and spectroscopic studies
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی تئوریک و عملی
پیش نمایش صفحه اول مقاله
Study of molecular interaction in the mixtures of benzene + methyl acrylate/butyl acrylate through dielectric and spectroscopic studies
چکیده انگلیسی
Binary mixtures of benzene + methyl acrylate/butyl acrylate were prepared over the entire composition range which were subjected to dielectric and spectroscopic (FTIR, 13C NMR and UV-vis) studies. The parameters such as Kirkwood correlation factor, excess dielectric constant etc. are interpreted with the aid of spectroscopic results which revealed the existence of blue and red shifting hydrogen bonds in both the mixtures. 13C NMR and excess free energy ∆ G favor the presence of self-associated molecular aggregates in neat methyl acrylate/butyl acrylate.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Molecular Liquids - Volume 214, February 2016, Pages 357-363
نویسندگان
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