کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
5410408 1506552 2016 8 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Uptake of pantoprazole drug residue from water using novel synthesized composite iron nano adsorbent
ترجمه فارسی عنوان
جذب پانتوپازول داروهای باقی مانده از آب با استفاده از نیترات سدیم کامپوزیتی نانو
کلمات کلیدی
پانوترازول، جذب، مدل سازی، سینتیک و ترمودینامیک، تصفیه آب، جذب نانو نانو کامپوزیت
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی تئوریک و عملی
چکیده انگلیسی
Pantoprazole drug residue is present in some water bodies leading to toxicity to human beings. The uptake of pantoprazole drug residue from water is reported on composite iron nano adsorbent. Adsorbent was prepared by green method and characterized by FTIR, XRD, SEM, TEM and EDX techniques. The pantoprazole concentrations in adsorption experiments were determined by HPLC on new generation Sunshell C18 column (150 × 4.61 mm; 2.6 μm). The optimized parameters were 30.0 min., 50 μg L− 1, 7.0, 1.0 g L− 1, and 25.0 °C as contact time, concentration, pH, adsorbent amounts and temperature. The data obeyed Langmuir, Freundlich, Temkin and Dubinin-Radushkevich isotherms. ΔG° values were − 9.53, − 9.57 and − 9.62 kJ/mol at 20, 25 and 30 °C temperatures. ΔH° and ΔS° values were − 3.39 and 20.19 × 10− 3. These magnitudes showed favorable and exothermic adsorption. Pseudo-first-order and liquid film diffusion mechanisms of the adsorption were reported. The reported adsorption method was fast, environmental friendly and low-priced due to its nature to be applicable under natural conditions of water resources. The developed method may be applicable for the removal of pantoprazole drug residue in natural water resources at pH 7.0 with low amount of adsorbent and contact time. The adsorption method may be used for pantoprazole removal from any water body at large and economic scale.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Molecular Liquids - Volume 218, June 2016, Pages 465-472
نویسندگان
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