کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5410614 | 1506559 | 2015 | 14 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Experimental, quantum chemical and Monte Carlo simulation studies on the corrosion inhibition of some alkyl imidazolium ionic liquids containing tetrafluoroborate anion on mild steel in acidic medium
دانلود مقاله + سفارش ترجمه
دانلود مقاله ISI انگلیسی
رایگان برای ایرانیان
کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی تئوریک و عملی
پیش نمایش صفحه اول مقاله

چکیده انگلیسی
The inhibition of mild steel corrosion in 1Â M HCl solution by some imidazolium-based ionic liquids (ILs), namely 1-ethyl-3-methylimidazolium tetrafluoroborate [EMIM]+[BF4]â, 1-butyl-2,3-dimethylimidazolium tetrafluoroborate [BDMIM]+[BF4]â and 1-decyl-3-methylimidazolium tetrafluoroborate [C10MIM]+[BF4]â was investigated using experimental and theoretical techniques. All the studied ILs showed appreciable inhibition efficiencies. Polarization measurements showed that the studied compounds are mixed-type inhibitors and the results obeyed Langmuir adsorption isotherm. Spectroscopic studies confirmed chemical interactions between mild steel and the ILs. Scanning electron microscopy images revealed that the inhibitors formed protective film on mild steel surface. The results of quantum chemical calculations and Monte Carlo simulations agree with experimental observations.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Molecular Liquids - Volume 211, November 2015, Pages 105-118
Journal: Journal of Molecular Liquids - Volume 211, November 2015, Pages 105-118
نویسندگان
Y. Sasikumar, A.S. Adekunle, L.O. Olasunkanmi, I. Bahadur, R. Baskar, M.M. Kabanda, I.B. Obot, E.E. Ebenso,