کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
5410772 1506562 2015 5 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Enhancement in the thermodynamic, electrical and optical properties of hexabutoxytriphenylene due to copper nanoparticles
ترجمه فارسی عنوان
افزایش خواص ترمودینامیکی، الکتریکی و نوری هگزابوتوکسیتریفن هایلن به علت نانوذرات مس
کلمات کلیدی
کریستال مایع، فاز شش ضلعی ستون، هسته های معطر، تراز هوموتوپروپیک، هدایت یونی، پلاسمون سطحی،
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی تئوریک و عملی
چکیده انگلیسی
In the present article, we have studied the effect of copper nano-particles on the thermal, optical and dielectric parameters of a liquid crystalline material 2,3,6,7,10,11-hexabutyloxytriphenylene (in short HAT4) showing wide temperature range (~ 65 °C) hexatic columnar mesophase. A composite has been prepared by dispersing 0.6 wt.% of copper nano-particles. UV-vis spectroscopy has been used to record the absorption spectra. It has been observed that the presence of copper nano-particles introduces surface plasmon resonance and reduces the optical band gap of HAT4. Though isotropic to mesophase transition temperature is unaffected but mesophase-crystal transition temperature has decreased and hence range of the mesophase has enhanced due to the presence of copper nano-particles. While dc conductivity has increased by about two orders of magnitudes, dielectric permittivity has also moderately increased. With the enhanced properties, HAT4-copper nano-particle composite is useful for one dimensional conduction and photovoltaic applications.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Molecular Liquids - Volume 208, August 2015, Pages 160-164
نویسندگان
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