کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5411016 | 1506568 | 2015 | 6 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Third derivative thermodynamic quantities of aqueous tetrahydrofuran at 25 °C
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موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی تئوریک و عملی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
We measured the excess chemical potential, μÎTHF, the excess partial molar enthalpy and entropy of solute tetrahydrofuran (THF), HETHF and SETHF, in THF-H2O at 25 °C. Using these second derivatives of G, we graphically evaluated the third derivative quantities; the enthalpic, entropic THF-THF interaction functions, HETHF-THF, and SETHF-THF. Using the literature density data, the effect of THF on the excess partial molar volume of THF, VETHF-THF, was also evaluated. Furthermore, we directly determined the partial molar entropy-volume cross fluctuation density of THF, δTHFSV, another third derivative quantity. By comparing the mole fraction dependence patterns of these third derivative quantities between the present THF-H2O with what we thought to be the weakest member of a hydrophobic mono-ol series, methanol (ME), we suggest that in spite of its larger non-polar surface area, THF is as amphiphilic as ME. A quantitative characterization and any difference between THF and ME ought to wait for characterization by the 1-propanol probing methodology developed by us [PCCP 15(2013) 14548-14565].
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Molecular Liquids - Volume 202, February 2015, Pages 40-45
Journal: Journal of Molecular Liquids - Volume 202, February 2015, Pages 40-45
نویسندگان
Koh Yoshida, Peter Westh, Akira Inaba, Motohiro Nakano, Yoshikata Koga,