کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5411022 | 1506568 | 2015 | 7 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Effect of 1-carboxymethyl-3-methylimidazolium chloride, [HOOCMMIM][Cl], ionic liquid on volumetric, acoustic and transport behavior of aqueous solutions of l-serine and l-threonine at TÂ =Â 298.15Â K
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی تئوریک و عملی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
Apparent molar volumes, VÏ, apparent molar isentropic compressibilities, Ks,Φ, and relative viscosities, ηr, for l-serine and l-threonine in aqueous solutions of 1-carboxymethyl-3-methylimidazolium chloride, [HOOCMMIM][Cl], and also aqueous solutions of [HOOCMMIM][Cl] have been obtained from solution density, sound velocity and viscosity measurements at T = 298.15 K and atmospheric pressure. These data are used to derive the standard partial molar volumes, VÏ0, hydration number, (nH), standard partial molar isentropic compressibilities, Ks,Φ0, and viscosity B-coefficients of l-serine and l-threonine in aqueous [HOOCMMIM][Cl] solutions and for [HOOCMMIM][Cl] in water. The corresponding quantities of transfer from water to aqueous solutions of [HOOCMMIM][Cl], (ÎVÏ0,ÎKS,Φ0,ÎB), have also been obtained. The trends of transfer volumes have been interpreted by cosphere overlap model.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Molecular Liquids - Volume 202, February 2015, Pages 79-85
Journal: Journal of Molecular Liquids - Volume 202, February 2015, Pages 79-85
نویسندگان
Mohammed Taghi Zafarani-Moattar, Behnaz Asadzadeh,