Structure and physico-chemical properties of three analogous ionic liquids containing magnesium chloride

► We reported structure of three ionic liquid analogous of ChCl-MgCl2-EG/Gl/urea. ► The physical chemical properties of three ionic liquid analogous were measured. ► The thermodynamic parameter such as ΔG*, ΔH* and ΔS* for viscous flow have been calculated.