کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5412810 | 1393450 | 2011 | 9 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Features of ion hydration and association in aqueous rubidium fluoride solutions at ambient conditions
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی تئوریک و عملی
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Features of ion hydration and association in aqueous rubidium fluoride solutions at ambient conditions Features of ion hydration and association in aqueous rubidium fluoride solutions at ambient conditions](/preview/png/5412810.png)
چکیده انگلیسی
Aqueous RbF solutions have been investigated at ambient conditions by dielectric relaxation spectroscopy (DRS) over the concentration range of 0 â¤Â c/M â¤Â 5 and by statistical mechanics (RISM integral equation theory) in the concentration range of 2.15-9.18 M. The behavior of the dielectric spectra and their characteristic parameters (dispersion amplitudes and relaxation times) is discussed, as well as the pair correlation functions and partial coordination numbers derived from statistical mechanics. The paper focuses on the influence of salt concentration on the features of ion hydration and association. The observed changes in the dielectric properties indicate a decrease of the effective hydration number from â¼Â 15-18 at infinite dilution to â¼Â 3.5 at 5 M and possibly weak association involving stable ion pairs at c â¤Â 0.5 M. A major finding is that both ions, Rb+ and Fâ, slow down surrounding water molecules, leading to the emergence of a separate “slow water” relaxation in the spectra. According to the analysis of RISM equilibrium properties, an average number of â¼Â 6 water molecules coordinates both Rb+ and Fâ at c = 2.15 M. This number decreases by â¼Â 19% for the cation and by â¼Â 10% for the anion as c growths up to 9.18 M. The RISM-data indicate a significant increase in the number of contact and solvent-separated ion pairs with increasing c. The possibility of ion clustering is discussed for concentrated RbF(aq) solutions.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Molecular Liquids - Volume 159, Issue 1, 15 February 2011, Pages 9-17
Journal: Journal of Molecular Liquids - Volume 159, Issue 1, 15 February 2011, Pages 9-17
نویسندگان
M.V. Fedotova, S.E. Kruchinin, H.M.A. Rahman, R. Buchner,