کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
5412831 1393451 2011 4 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
New version of the fluctuation Hamiltonian for liquids near the critical point
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی تئوریک و عملی
پیش نمایش صفحه اول مقاله
New version of the fluctuation Hamiltonian for liquids near the critical point
چکیده انگلیسی
We propose a new canonical form of the fluctuational Hamiltonian which takes into account the fact that in the vicinity of the critical point there are two fluctuating fields. They are the field of the number density and the entropy. The proposed canonical form is based on the D5 catastrophe. In contrast to the standard approach of Landau-Ginzburg Hamiltonian which is based on A3 catastrophe the canonical form proposed for the fluctuational Hamiltonian naturally includes the asymmetric coupling between the fields.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Molecular Liquids - Volume 158, Issue 3, 1 February 2011, Pages 166-169
نویسندگان
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