کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
5412964 1506612 2010 6 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Hydrophobic and low-density amino acid ionic liquids
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی تئوریک و عملی
پیش نمایش صفحه اول مقاله
Hydrophobic and low-density amino acid ionic liquids
چکیده انگلیسی
A series of tetraalkylphosphonium amino acid salts was synthesized to determine the effect of ion structure, in particular the length of alkyl chains, on physico-chemical properties such as density, viscosity, glass transition temperature, and decomposition temperature. The resulting alkylphosphonium amino acid ionic liquids (AAILs) all had low density, from 0.886 to 0.945 g cm− 3 at 25 °C. The density was tunable by varying the alkyl-chain length, regardless of the symmetry of the phosphonium cations. When the alkyl chains on the phosphonium cation were hexyl or longer, the AAILs were phase-separated upon mixing with water because of their hydrophobicity, and floated on top of the water phase. The water content in the ILs depended on the amino acid side chains and on the alkyl-chain length on the cations.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Molecular Liquids - Volume 153, Issues 2–3, 15 May 2010, Pages 133-138
نویسندگان
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