کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5413265 | 1506621 | 2008 | 7 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Thermodynamics of mixtures containing polycyclic aromatic hydrocarbons
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی تئوریک و عملی
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چکیده انگلیسی
The DISQUAC group contribution model has been applied to the study of mixtures containing a polycyclic aromatic compound, naphthalene, phenanthrene, anthracene or pyrene, and an organic solvent, n-alkane, cyclohexane or 1-alkanol. The corresponding interaction parameters are reported. Systems with alkanes are characterized by dispersive parameters only. For naphthalene + 1-alkanol mixtures, the aromatic/OH contacts are represented by dispersive and quasichemical parameters. The latter are equal to those encountered in 1-alkanol + benzene, or + alkylbenzene mixtures for such contacts. DISQUAC provides good results on molar excess enthalpies, HE, solid-liquid equilibria, SLE, and vapor-liquid equilibria over a wide range of temperature for the investigated mixtures. In PAH + n-alkane systems, there is an enthalpy-entropy compensation effect in solutions with long alkanes, and no Patterson's effect is observed. Solubility of naphthalene in hexane or 1-hexanol is similar, and lower than that of 1-alkanol in alkane. This seems to indicate that interactions between unlike molecules are not so relevant as in 1-alkanol + benzene mixtures.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Molecular Liquids - Volume 143, Issues 2â3, 20 October 2008, Pages 134-140
Journal: Journal of Molecular Liquids - Volume 143, Issues 2â3, 20 October 2008, Pages 134-140
نویسندگان
Juan Antonio González, Maciej Zawadzki, Urszula Domanska,