کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5413525 | 1506630 | 2007 | 4 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
The phase diagram of confined fluids
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی تئوریک و عملی
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: The phase diagram of confined fluids The phase diagram of confined fluids](/preview/png/5413525.png)
چکیده انگلیسی
The phase diagram of a Lennard-Jones fluid confined in a quenched disordered structure is studied by Grand-Canonical Monte Carlo simulation. The matrix is generated from an off-lattice diffusion-limited cluster-cluster aggregation procedure to represent a highly porous silica aerogel with a fractal structure. The Multicanonical Ensemble Sampling technique combined with the histogram reweighting method makes possible to build the liquid-vapor coexistence curve which is narrower than in the bulk. A shouldering on the liquid side of the phase diagram is observed which indicates the possibility of a second transition. Preliminary results for a larger system indicate the presence of a liquid-liquid coexistence besides the gas-liquid transition.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Molecular Liquids - Volume 134, Issues 1â3, 15 May 2007, Pages 90-93
Journal: Journal of Molecular Liquids - Volume 134, Issues 1â3, 15 May 2007, Pages 90-93
نویسندگان
V. De Grandis, P. Gallo, M. Rovere,