کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
5413599 1506632 2007 5 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Field theoretical approach to the liquid state. Elements of comprehension of the role of the ideal entropy
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی تئوریک و عملی
پیش نمایش صفحه اول مقاله
Field theoretical approach to the liquid state. Elements of comprehension of the role of the ideal entropy
چکیده انگلیسی
In a series of papers we have introduced a field theoretical approach to describe the liquid state. The formalism introduces a simple Hamiltonian which includes the ideal gas free energy and the standard interaction potential between particles coupling the fields. In this paper, we discuss the role and the importance of the ideal term in this formalism. We compare our approach to the standard liquid state theory and another approach based on a field description, the density functional theory where an identical functional appears. The comparison shows that field theory sheds new light on the role of the ideal entropy an aspect which is traditionally discarded in favor of a viewpoint focusing on the interaction potential.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Molecular Liquids - Volumes 131–132, 15 March 2007, Pages 48-52
نویسندگان
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