کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5413608 | 1506632 | 2007 | 8 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
A structural study of the N,Nâ²-dimethylpropyleneurea solvated zinc(II) and cadmium(II) ions in solution and crystalline state
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی تئوریک و عملی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
The structures of the N,Nâ²-dimethylpropyleneurea (DMPU) solvated zinc(II) and cadmium(II) ions have been studied in solution by extended X-ray absorption fine structure (EXAFS) and large angle X-ray scattering (LAXS), and in solid state as the trifluoromethanesulfonate salts by EXAFS and crystallography. The DMPU solvated zinc(II) ion is four-coordinated in a tetrahedral fashion with a mean Zn-O bond distance of 1.925(6)Â Ã
in solid state, while the mean Zn-O bond distance is much longer in solution, 1.99(2)Â Ã
, suggesting that a five-coordinated solvate complex is dominating. As this Zn-O bond distance is somewhat shorter than expected for a five-coordinated zinc(II) complex the presence of a transient four-coordinated solvate complex in small amounts is possible. The DMPU solvated cadmium(II) ion is six-coordinated in an octahedral fashion in the solid state with a mean Cd-O bond distance of 2.260(9)Â Ã
. The crystal structure displays severe disorder of both the hexakis(N,Nâ²-dimethylpropyleneurea)cadmium and trifluoromethanesulfonate ions. In this case, the mean Cd-O bond distance is slightly shorter in solution, 2.24(1)Â Ã
, which may indicate the existence of a transient dissociative five-coordinated species.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Molecular Liquids - Volumes 131â132, 15 March 2007, Pages 105-112
Journal: Journal of Molecular Liquids - Volumes 131â132, 15 March 2007, Pages 105-112
نویسندگان
Daniel Lundberg, Lars Eriksson, Paola D'Angelo, Ingmar Persson,