کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5413773 | 1506638 | 2006 | 10 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Universality and corresponding state behaviour in the phase diagrams of alcohol solutions of ionic liquids with the BF4â anion
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی تئوریک و عملی
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Universality and corresponding state behaviour in the phase diagrams of alcohol solutions of ionic liquids with the BF4â anion Universality and corresponding state behaviour in the phase diagrams of alcohol solutions of ionic liquids with the BF4â anion](/preview/png/5413773.png)
چکیده انگلیسی
The phase diagrams of solutions of room temperature ionic liquids butyl- and hexyl-methylimidazolium tetrafluoroborate (Cnmim BF4) in various alcohols, reported in the literature, are analysed by means of a novel function, which presumes Ising behaviour and the applicability of the rectilinear diameter rule. The fit parameters obtained (critical temperature, critical composition, amplitude of the phase diagram, and slope of the diameter) allow for a good representation of the data. Estimates of the critical point data are in good agreement with that determined independently by the equal volume criteria. Two different types of corresponding state analysis are carried out.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Molecular Liquids - Volume 125, Issues 2â3, 15 April 2006, Pages 164-173
Journal: Journal of Molecular Liquids - Volume 125, Issues 2â3, 15 April 2006, Pages 164-173
نویسندگان
Wolffram Schröer,