کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5414447 | 1506726 | 2015 | 10 صفحه PDF | دانلود رایگان |
- Novel hot cell heated up to 900Â K used in VUV-FTS at synchrotron SOLEIL.
- Recorded N2 and CO spectra including high-J states up to J â¼Â 50.
- N2 spectra analysis using coupled Schrödinger equations.
- Accurate deperturbation analysis of CO spectra.
- Results relevant in astrophysical or (exo-)planetary atmospheric physics.
Photoabsorption spectra of N2 and CO were recorded at 900 K, using the vacuum-ultraviolet Fourier-transform spectrometer at the DESIRS beamline of synchrotron SOLEIL. These high-temperature and high-resolution measurements allow for precise determination of line wavelengths, oscillator strengths, and predissociative line broadening of highly-excited rotational states with J up to about 50, and also vibrational hot bands. In CO, the perturbations of the A1Î -X1Σ+ vibrational bands (0,0) and (1,0) were studied, as well as the transitions to perturbing optically-forbidden states e3Σ-,d3Î,D1Î and aâ²3Σ+. In N2, we observed line shifts and broadening in several b1Î u-X1Σg+ bands due to unobserved forbidden states of 3Î u symmetry. The observed state interactions are deperturbed and, for N2, used to validate a coupled-channels model of the interacting electronic states. These data are appropriate for use in astrophysical or (exo-)planetary atmospheric applications where high temperatures are important and in future spectroscopic models of these molecules.
Journal: Journal of Molecular Spectroscopy - Volume 315, September 2015, Pages 137-146