کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5415452 | 1393758 | 2009 | 11 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
High resolution study of the 3ν1 band of SO2
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی تئوریک و عملی
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: High resolution study of the 3ν1 band of SO2 High resolution study of the 3ν1 band of SO2](/preview/png/5415452.png)
چکیده انگلیسی
The second overtone band 3ν1 of sulfur dioxide has been studied for the first time with high resolution rotation-vibration spectroscopy. About 3000 transitions involving about 900 upper state energy levels with Jmax.=66andKamax.=24 have been assigned to the 3ν1 band. In the analysis, an effective Hamiltonian taking into account accidental interactions between the vibrational states (3 0 0), (2 2 0), and (0 4 1) was used. The Watson operator in A-reduction and Ir representation was used in the diagonal blocks of the Hamiltonian. As the result of analysis a set of parameters reproducing the initial experimental data with the rms = 0.00028 cmâ1 was obtained.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Molecular Spectroscopy - Volume 255, Issue 2, June 2009, Pages 111-121
Journal: Journal of Molecular Spectroscopy - Volume 255, Issue 2, June 2009, Pages 111-121
نویسندگان
O.N. Ulenikov, E.S. Bekhtereva, V.-M. Horneman, S. Alanko, O.V. Gromova,