کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5415510 | 1393761 | 2008 | 5 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
FTIR spectra and rovibrational analysis of the ν11 band of trans-ClHCCHF and ν10 of trans-ClHCCDF
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی تئوریک و عملی
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: FTIR spectra and rovibrational analysis of the ν11 band of trans-ClHCCHF and ν10 of trans-ClHCCDF FTIR spectra and rovibrational analysis of the ν11 band of trans-ClHCCHF and ν10 of trans-ClHCCDF](/preview/png/5415510.png)
چکیده انگلیسی
High-resolution Fourier transform infrared spectra of natural trans-ClHCCHF and of its isotopologue trans-ClHCCDF have been recorded in the region between 700 and 1150 cmâ1 with the purpose to analyze the ν11 fundamental of the main species and the ν10 of its deuterated compound. Both bands, of symmetry species Aâ³, present c-type envelope absorptions. Beside the expected features, the K structure of the P(J), Q(J), and R(J) manifolds was resolved and identified; the assignment of the rovibrational transitions was extended up to J = 92 and Ka = 13 for the trans-35ClHCCHF and up to J = 86 and Ka = 10 for trans-35ClHCCDF. More than 2900 and 2700 lines for the main and deuterated species, respectively, were analyzed by a least-squares procedure and reliable spectroscopic molecular parameters were determined for both isotopologues.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Molecular Spectroscopy - Volume 252, Issue 1, November 2008, Pages 47-51
Journal: Journal of Molecular Spectroscopy - Volume 252, Issue 1, November 2008, Pages 47-51
نویسندگان
Alberto Gambi, Paolo Stoppa, Filippo Tamassia,