کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
5415585 1506769 2008 6 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
The pure rotational spectrum of pivaloyl chloride, (CH3)3CCOCl, between 800 and 18 800 MHz
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی تئوریک و عملی
پیش نمایش صفحه اول مقاله
The pure rotational spectrum of pivaloyl chloride, (CH3)3CCOCl, between 800 and 18 800 MHz
چکیده انگلیسی
A search accelerated correct intensity Fourier transform microwave (SACI-FTMW) spectrometer has been used to rapidly record the rotational spectrum of pivaloyl chloride between 8 and 18 GHz. Both a radio frequency and regular cavity-based instrument have then been used to obtain high resolution measurements below 4 GHz and in the 4-18 GHz regions, respectively. Rotational constants, centrifugal distortion constants, and chlorine nuclear quadrupole coupling constants have been determined for both the 35Cl and 37Cl isotopologues. The spectrum provides no evidence concerning internal rotation in the molecule.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Molecular Spectroscopy - Volume 251, Issues 1–2, September–October 2008, Pages 378-383
نویسندگان
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