کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5415868 | 1393782 | 2008 | 24 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
On the study of the vibrational energy levels of Arsine molecule
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی تئوریک و عملی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
We compare two formalisms applied to the vibrational modes of the molecule of AsH3 of C3v molecular symmetry group. Indeed, the close stretching modes of this molecule may be considered as those of a three-dimensional oscillator whereas the bending modes may be considered either as a one-dimensional oscillator of symmetry A1 and a two-dimensional oscillator of symmetry E or as an approximate three-dimensional oscillator. So, we have applied the U(p + 1) formalism to the both stretching and bending modes and introduced coupling terms acting on an appropriate coupled vibrational basis through a local mode formalism. We have then compared the result of our fitting with those obtained with the coupling of a local mode formalism adapted to the stretching vibrations with a normal mode formalism for the bending ones. Finally we compare our results with other methods recently proposed in the literature.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Molecular Spectroscopy - Volume 247, Issue 1, January 2008, Pages 1-24
Journal: Journal of Molecular Spectroscopy - Volume 247, Issue 1, January 2008, Pages 1-24
نویسندگان
N.A. Sanzharov, C. Leroy, O.N. Ulenikov, E.S. Bekhtereva,