کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5415889 | 1393783 | 2007 | 6 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Triply hydrogen bonded van der Waals complexes: CH2F2â¯CF2CH2 and CH2F2â¯CF2CHF
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی تئوریک و عملی
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چکیده انگلیسی
The results of molecular beam Fourier transform microwave (FTMW) investigations of the van der Waals complexes of difluoromethane with 1,1-difluoroethene (DFE) and trifluoroethene (TFE) are reported. The rotational parameters of the complexes have been interpreted in terms of a Cs geometry with the two H or F atoms of CH2F2 lying out of the Ïv symmetry plane of the complexes. The complexes are bound by three hydrogen bonds, of which one is the stronger C-Fâ¯H-C type, and two are the weaker C-Hâ¯Fâ¯H-C or C-Fâ¯Hâ¯F-C types for DFM-DFE or DFM-TFE, respectively. The most notable difference in the two complexes is that the out of plane atoms are two hydrogens for DFM-DFE, but are two fluorines for DFM-TFE. Additional information on the structure and hydrogen bonding has been obtained from ab initio calculations.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Molecular Spectroscopy - Volume 242, Issue 2, April 2007, Pages 150-155
Journal: Journal of Molecular Spectroscopy - Volume 242, Issue 2, April 2007, Pages 150-155
نویسندگان
Yoshio Tatamitani, Kenji Yamanou, Hideaki Kanno, Teruhiko Ogata,