کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5416151 | 1393799 | 2006 | 12 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Combined analysis of the high sensitivity Fourier transform and ICLAS-VeCSEL absorption spectra of D2O between 8800 and 9520Â cmâ1
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی تئوریک و عملی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
The absorption spectrum of dideuterated water, D2O, has been recorded between 8800 and 9520Â cmâ1 by intracavity laser absorption spectroscopy (ICLAS) based on a vertical external cavity system emitting laser (VeCSEL) and by high sensitivity Fourier Transform spectroscopy. The combined analysis of the spectra has allowed attributing 1223 transitions to the D2O species. The spectrum assignment was performed on the basis of the recent results of variational calculations based on an optimized potential energy surface of D2O. A set of 687 energy levels was derived from transitions assigned to eight upper vibrational states, 577 of them being reported for the first time. A detailed line list has been generated. The line intensities were retrieved mainly from the FTS spectrum and the absolute integrated intensities of the 2v1Â +Â v2Â +Â v3 and the v2Â +Â 3v3 bands dominating the spectrum have been determined.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Molecular Spectroscopy - Volume 238, Issue 1, July 2006, Pages 79-90
Journal: Journal of Molecular Spectroscopy - Volume 238, Issue 1, July 2006, Pages 79-90
نویسندگان
O.V. Naumenko, O. Leshchishina, S. Shirin, A. Jenouvrier, S. Fally, A.C. Vandaele, E. Bertseva, A. Campargue,