کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5416827 | 1506922 | 2009 | 5 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
The sign preference in sulfuric acid nucleation
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی تئوریک و عملی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
The binding of sulfuric acid to a series of anions and cations of varying chemical complexity is studied using quantum chemical methods. Sulfuric acid is bound much more strongly to anions than cations, as expected from structural and general chemical considerations, and previous computational studies on charged sulfuric acid-water clusters. The results are likely to explain the sign effect observed in atmospheric nucleation phenomena, and indicate that the first steps of ion-induced nucleation are controlled by the specific chemical interactions between the core ion and the condensing molecules rather than by general physical (e.g. electrostatic) effects.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Molecular Structure: THEOCHEM - Volume 901, Issues 1â3, 15 May 2009, Pages 169-173
Journal: Journal of Molecular Structure: THEOCHEM - Volume 901, Issues 1â3, 15 May 2009, Pages 169-173
نویسندگان
Theo Kurtén, Ismael K. Ortega, Hanna Vehkamäki,