کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
5417728 1506937 2008 4 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
A test of empirical correction to site preference: DFT calculations for CO adsorption on Co(0 0 0 1) surface
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی تئوریک و عملی
پیش نمایش صفحه اول مقاله
A test of empirical correction to site preference: DFT calculations for CO adsorption on Co(0 0 0 1) surface
چکیده انگلیسی
Within density functional theory (DFT) calculations, we have studied the influence of different exchange and correlation functional on the site preference for CO adsorption on Co(0 0 0 1) surface. All functional results identify atop and hollow sites as the favored sites with degenerate energy, also present almost identical adsorption geometries and vibrational frequencies for CO adsorption in each high symmetry site. However, based on empirical correction to adsorption energy, atop site is uniquely identified as the most favorable site, in perfect agreement with experimental results. This work provides another correct site preference with empirical correction to adsorption energy.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Molecular Structure: THEOCHEM - Volume 864, Issues 1–3, 15 September 2008, Pages 68-71
نویسندگان
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