کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5417728 | 1506937 | 2008 | 4 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
A test of empirical correction to site preference: DFT calculations for CO adsorption on Co(0Â 0Â 0Â 1) surface
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی تئوریک و عملی
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چکیده انگلیسی
Within density functional theory (DFT) calculations, we have studied the influence of different exchange and correlation functional on the site preference for CO adsorption on Co(0Â 0Â 0Â 1) surface. All functional results identify atop and hollow sites as the favored sites with degenerate energy, also present almost identical adsorption geometries and vibrational frequencies for CO adsorption in each high symmetry site. However, based on empirical correction to adsorption energy, atop site is uniquely identified as the most favorable site, in perfect agreement with experimental results. This work provides another correct site preference with empirical correction to adsorption energy.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Molecular Structure: THEOCHEM - Volume 864, Issues 1â3, 15 September 2008, Pages 68-71
Journal: Journal of Molecular Structure: THEOCHEM - Volume 864, Issues 1â3, 15 September 2008, Pages 68-71
نویسندگان
Shu-Hong Ma, Xiao-Tao Zu, Zhao-Yong Jiao, Xian-Zhou Zhang,