کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5419382 | 1506988 | 2006 | 6 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Competition between inter- and intra- molecular energy exchanges in a simple quantum model of a dimer
دانلود مقاله + سفارش ترجمه
دانلود مقاله ISI انگلیسی
رایگان برای ایرانیان
کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی تئوریک و عملی
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Competition between inter- and intra- molecular energy exchanges in a simple quantum model of a dimer Competition between inter- and intra- molecular energy exchanges in a simple quantum model of a dimer](/preview/png/5419382.png)
چکیده انگلیسی
We propose a fully quantum model to describe the dynamics of a possible radiationless energy transfer process between identical and nearly localized molecules or monomers coupled through a dipole-dipole term. The system is studied as an environmentally isolated dimeric pair and we find that its dynamics exhibits a competition between the process ruling out the transfer of energy among different degrees of freedom of a given monomer and the one steering the intermolecular passage of excitations from a monomer to the other one. Such a competition is quantitatively characterized investigating on the temporal behaviour of quantum covariances of some couples of appropriate observables having a clear physical meaning.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Molecular Structure: THEOCHEM - Volume 769, Issues 1â3, 14 September 2006, Pages 3-8
Journal: Journal of Molecular Structure: THEOCHEM - Volume 769, Issues 1â3, 14 September 2006, Pages 3-8
نویسندگان
T. Cusati, A. Napoli, A. Messina,