کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
5420625 1395456 2009 5 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Spin-lattice relaxation dispersion in polymers: Dipolar-interaction components and short- and long-time limits
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی تئوریک و عملی
پیش نمایش صفحه اول مقاله
Spin-lattice relaxation dispersion in polymers: Dipolar-interaction components and short- and long-time limits
چکیده انگلیسی
The Mori-Zwanzig projection operator technique was employed to derive the effective Hamiltonian for spin-segment coupling. The fluctuations of this operator are responsible for spin-lattice relaxation in polymer chains. In detail, dipolar interaction of spins is rigorously analyzed by components representing fluctuations of the Kuhn segment end-to-end vectors and local fluctuations on a length scale shorter than the root mean square Kuhn segment length. The former correspond to the usual coarse-grain picture of polymer chain mode theories. It is shown that these non-local chain modes dominate proton spin-lattice relaxation dispersion of flexible polymers at frequencies up to about 108 Hz. A corresponding evaluation of experimental data for polybutadiene melts is presented.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Solid State Nuclear Magnetic Resonance - Volume 35, Issue 3, June 2009, Pages 147-151
نویسندگان
, , , ,