کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5420993 | 1507517 | 2006 | 5 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Solid-state NMR as an analytical tool: Quantitative aspects
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی تئوریک و عملی
پیش نمایش صفحه اول مقاله
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چکیده انگلیسی
Analytical methods based on solid-state NMR are becoming increasingly popular. However, these flourishing activities bring up the issue of how accurately NMR can assess an analyte proportion in a solid sample. The use of a chemical intensity reference for this purpose is a natural but often unsuitable choice, due to sample stability or preciousness. We propose here a protocol to perform quantitative measurements in solid-state NMR, by calibration of the circuit response through a low-power pulse injected during the acquisition (the so-called ERETIC method). Although this method has been in use for some time in liquid-phase and in vivo NMR, we point out here some peculiarities and useful applications typical of solids. Namely, the temperature dependence of the signal intensity imposes care in the application to MAS experiments.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Solid State Nuclear Magnetic Resonance - Volume 29, Issues 1â3, February 2006, Pages 214-218
Journal: Solid State Nuclear Magnetic Resonance - Volume 29, Issues 1â3, February 2006, Pages 214-218
نویسندگان
Fabio Ziarelli, Stefano Caldarelli,